You'll hear this from a lot of bros but it's about rapport and how you make them feel. If you make them feel that you're a sleaze and a bad guy in general, they will not do you any favours.
If you're a gentleman and connect with them on more than just a financial level, they are more likely to go ahead with you're request.
A tip from me: always try the first pic with BOTH you and her (can be a little tricky with an iPhone). This will give her a sense of security that you are less likely to paste it all over the interenet cos it's got your face on it too
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But mainly, it's less threatening. Once she's warmed to that take more pics and remember, they DON'T have to be nude pics.
If it's a company policy (like in China MPs) that they cannot take pics then just respect that fact...