Peeing after sex does not prevent sexually transmitted infections (STIs). People contract STIs by absorbing bacteria through the mucous membranes inside their bodies during sexual intercourse. Peeing after sex will not prevent these bacteria from entering the body. A urinary tract infection (UTI) comes from a different bacteria travelling up the urethra. The two types of infections are different.
There is no recommended time to pee after having sex, although some anecdotal sources suggest peeing within 30 minutes after sex. In general, the sooner people pee after sex, the sooner they can flush out bacteria before it travels up the urethra. But this MIGHT only prevent a UTI, not an STD.
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